Reactions of 5-Indolizyl Lithium Compounds with Some Bielectrophiles.

نویسندگان

  • Sergey A Rzhevskii
  • Victor B Rybakov
  • Victor N Khrustalev
  • Eugene V Babaev
چکیده

Abstract: Indolizyl-5-lithium anions react with succinic and phtalic anhidrides giving 1,4-keto acids, with oxallyl chloride giving 1,2-diketone, and with ethyl pyruvate giving 1,2-hydroxyacid. However, with α-halocarbonyl compounds, they react in different ways, forming the products of selective bromination at C-5 (with α-bromo ketones and esters of α-bromo acids) and 5-chloroacetyl indolizines.

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عنوان ژورنال:
  • Molecules

دوره 22 4  شماره 

صفحات  -

تاریخ انتشار 2017